بسم الله الرحمن الرحيم
Chemistry of Nanocarbons
By
Takeshi Akasaka, Fred Wudl, Shigeru Nagase
Publisher: Wiley
Number Of Pages: 526
Publication Date: 2010-08-17
ISBN-10 / ASIN: 0470721952
ISBN-13 / EAN: 9780470721957
Product Description
During the last decade, fullerenes and carbon nanotubes have attracted special interest as new nanocarbons with novel properties. Because of their hollow caged structure, they can be used as containers for atoms and molecules, and nanotubes can be used as miniature test-tubes.
Chemistry of Nanocarbons presents the most up-to-date research on chemical aspects of nanometer-sized forms of carbon, with emphasis on fullerenes, nanotubes and nanohorns. All modern chemical aspects are mentioned, including noncovalent interactions, supramolecular assembly, dendrimers, nanocomposites, chirality, nanodevices, host-guest interactions, endohedral fullerenes, magnetic resonance imaging, nanodiamond particles and graphene. The book covers experimental and theoretical aspects of nanocarbons, as well as their uses and potential applications, ranging from molecular electronics to biology and medicine.
TABLE OF CONTENTS
Preface
List of Contributors
1 Noncovalent Functionalization of Carbon Nanotubes
Claudia Backes and Andreas Hirsch
1.1 Introduction
1.2 Overview of Functionalization Methods
1.3 The Noncovalent Approach
1.4 Conclusion
2 Supramolecular Assembly of Fullerenes and Carbon Nanotubes Hybrids
Mª Ángeles Herranz, Beatriz M. Illescas, Emilio M. Pérez and Nazario Martín
2.1 Introduction
2.2 Hydrogen Bonded C60•Donor ensembles
2.3 Concave exTTF derivatives as recognizing motifs for fullerene
2.4 Non-Covalent Functionalization of Carbon Nanotubes
2.5 Summary and Outlook
Acknowledgements
References
3 Properties of Fullerene-Containing Dendrimers
Juan-José CID Martin and Jean-François Nierengarten
3.1 Introduction
3.2 Dendrimers with a fullerene core
3.3 Fullerene-rich dendrimers
3.4 Conclusions
Acknowledgements
References
4 Novel Electron Donor Acceptor Nanocomposites
Hiroshi Imahori, Dirk M. Guldi and Shunichi Fukuzumi
4.1 Introduction
4.2 Electron donor-fullerene composites
4.3 Carbon Nanotubes
4.4 Other nanocarbon composites
References
5 Higher Fullerenes: Chirality and Covalent Adducts
Agnieszka Kraszewska, François Diederich, and Carlo Thilgen
5.1 Introduction
5.2 The Chemistry of C70
5.3 The Higher Fullerenes Beyond C70
5.4 Concluding Remarks
Acknowledgements
References
6 Application of Fullerenes to Nanodevices
Yutaka Matsuo and Eiichi Nakamura
6.1 Introduction
6.2 Synthesis of Transition Metal Fullerene Complexes
6.3 Organometallic Chemistry of Metal Fullerene Complexes
6.4 Synthesis of Multimetal Fullerene Complexes
6.5 Supramolecular Structures of Penta(organo)[60]fullerene Derivatives
6.6 Reduction of Penta(organo)[60]fullerenes to Generate Polyanions
6.7 Photoinduced Charge Separation
6.8 Photocurrent-Generating Organic and Organometallic Fullerene Derivatives
6.9 Conclusion
References
7 Supramolecular Chemistry of Fullerenes - Host Molecules for Fullerenes on the Basis of p-p Interaction
Takeshi Kawase
7.1 Introduction
7.2 Fullerenes as an Electron Acceptor
7.3 Host Molecules Composed of Aromatic p-systems
7.4 Complexes with Host Molecules based on Porphyrin p Systems
7.5 Complexes with Host Molecules bearing a Cavity Consisting of Curved p System
7.6 The nature of the Supramolecular property of fullerenes
References
8 Molecular Surgery toward Organic Synthesis of Endohedral Fullerenes
Michihisa Murata, Yasujiro Murata, and Koichi Komatsu
8.1 Introduction
8.2 Molecular-Surgery Synthesis of Endohedral C60 Encapsulating Molecular Hydrogen
8.3 Chemical Functionalization of H2@C60
8.4 Utilization of the Encapsulated H2 as an NMR Probe
8.5 Physical Properties of an Encapsulated H2 in C60
8.6 Molecular-Surgery Synthesis of Endohedral C70 Encapsulating Molecular Hydrogen
8.7 Outlook
References
9 New Endohedral Metallofullerenes: Trimetallic Nitride Endohedral Fullerenes
Marilyn M. Olmstead, Alan L. Balch, Julio R. Pinzon, Luis Echegoyen, Harry W. Gibson and Harry C. Dorn
9.1 Discovery, Preparation and Purification
9.2 Structural Studies
9.3 13C NMR studies of Trimetallic Nitride Endohedral Metallofullerenes (TNT-EMFs)
9.4 Reactivity of Trimetallic Nitride Endohedral Metallofullerenes (TNT-EMFs)
9.5 Summary and conclusions
References
10 Recent Progress in Chemistry of Endohedral Metallofullerenes
Takahiro Tsuchiya, Takeshi Akasaka and Shigeru Nagase
10.1 Introduction
10.2 Chemical derivatization of mono-metallofullerenes
10.3 Chemical derivatization of di-metallofullerenes
10.4 Chemical derivatization of trimetallic nitride template fullerene
10.5 Chemical derivatization of metallic carbaide fullerene
10.6 Missing metallofullerenes
10.7 Supramolecular chemistry
10.8 Conclusion
References
11 Gadonanostructures as Magnetic Resonance Imaging Contrast Agents
Jeyarama S. Ananta and Lon J. Wilson
11.1 Magnetic Resonance Imaging (MRI) and the Role of Contrast Agents (CAs)
11.2 The Advantages of Gadonanostructures as MRI Contrast Agent Synthons
11.3 Gadofullerenes as MRI Contrast agents
11.4 Understanding the Relaxation Mechanism of Gadofullerenes
11.5 Gadonanotubes as MRI Contrast Agents
Acknowledgements
References
12 Chemistry of soluble carbon nanotubes-fundamental and applications
Tsuyohiko Fujigaya and Naotoshi Nakashima
12.1 Introduction
12.2 Characterizations of dispersion state
12.3 Solubilization by small molecules
12.4 Solubilization by polymers
12.5 Nanotube/polymer hybrids/composites
12.6 Summary
References
13 Functionalization of Carbon Nanotubes for Nanoelectronic and Photovoltaic Applications
Stéphane Campidelli and Maurizio Prato
13.1 Introduction
13.2 Functionalization of carbon nanotubes
13.3 Properties and Applications
13.4 Conclusion
References
14 Dispersion and Separation of Single-walled Carbon Nanotubes
Yutaka Maeda, Takeshi Akasaka, Jing Lu and Shigeru Nagase
14.1 Introduction
2. 14.2 Dispersion of SWNTs
3. 14.3 Purification and separation of SWNTs using amine
14.4 Conclusion
15 Molecular Encapsulations into Interior Spaces of Carbon Nanotubes and Nanohorns
T. Okazaki, S. Iijima and M. Yudasaka
15.1 Introduction
15.2 SWCNT nanopeapods
15.3 Material incorporation and release in/from SWNH
15.4 Summary
References
16 Carbon Nanotube for Imaging of Single Molecules in Motion
Eiichi Nakamura
16.1 Introduction
16.2 Electron Microscopic Observation of Small Molecules
16.3 TEM Imaging of Alkyl Carborane Molecules
16.4 Alkyl Chain Passing Through a Hole
16.5 3D Structural Information on Pyrene Amide Molecule
16.6 Complex Molecule 4 Fixed outside of Nanotube
16.7 Conclusion
Acknowledgements
References
17 Chemistry of Single-Nano Diamond Particles
Eiji Ōsawa
17.1 Introduction
17.2 Geometrical Structure
17.3 Electronic Structure
17.4 Properties
17.5 Applications
17.6 Recollection and perspectives
Acknowledgements
References
18 Properties of p-electrons in Graphene Nanoribbons and Nanographenes
De-en Jiang, Xingfa Gao, Shigeru Nagase and Zhongfang Chen
18.1 Introduction
18.2 Edge effects in graphene nanoribbons and nanographenes
18.3 Electronic and magnetic properties of graphene nanoribbons and nanographenes
18.4 Outlook
Acknowledgements
References
19 Carbon Nano Onions
Luis Echegoyen, Angy Ortiz, Manuel N. Chaur and Amit J. Palkar
19.1 Introduction
19.2 Physical Properties of Carbon Nano Onions Obtained from Annealing
19.3 Raman Spectroscopy of Carbon Nano Onions Preparing by Annealing Nanodiamond
19.4 Electron Paramagnetic Resonance Spectroscopy
19.5 Carbon Nano Onions Prepared from Arcing Graphite Underwater
19.6 Reactivity of Carbon Nano Onions (CNOs)
19.7 Potential Applications of CNOs
Acknowledgements
References
Index
LinK
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Chemistry of Nanocarbons
By
Takeshi Akasaka, Fred Wudl, Shigeru Nagase
Publisher: Wiley
Number Of Pages: 526
Publication Date: 2010-08-17
ISBN-10 / ASIN: 0470721952
ISBN-13 / EAN: 9780470721957
Product Description
During the last decade, fullerenes and carbon nanotubes have attracted special interest as new nanocarbons with novel properties. Because of their hollow caged structure, they can be used as containers for atoms and molecules, and nanotubes can be used as miniature test-tubes.
Chemistry of Nanocarbons presents the most up-to-date research on chemical aspects of nanometer-sized forms of carbon, with emphasis on fullerenes, nanotubes and nanohorns. All modern chemical aspects are mentioned, including noncovalent interactions, supramolecular assembly, dendrimers, nanocomposites, chirality, nanodevices, host-guest interactions, endohedral fullerenes, magnetic resonance imaging, nanodiamond particles and graphene. The book covers experimental and theoretical aspects of nanocarbons, as well as their uses and potential applications, ranging from molecular electronics to biology and medicine.
TABLE OF CONTENTS
Preface
List of Contributors
1 Noncovalent Functionalization of Carbon Nanotubes
Claudia Backes and Andreas Hirsch
1.1 Introduction
1.2 Overview of Functionalization Methods
1.3 The Noncovalent Approach
1.4 Conclusion
2 Supramolecular Assembly of Fullerenes and Carbon Nanotubes Hybrids
Mª Ángeles Herranz, Beatriz M. Illescas, Emilio M. Pérez and Nazario Martín
2.1 Introduction
2.2 Hydrogen Bonded C60•Donor ensembles
2.3 Concave exTTF derivatives as recognizing motifs for fullerene
2.4 Non-Covalent Functionalization of Carbon Nanotubes
2.5 Summary and Outlook
Acknowledgements
References
3 Properties of Fullerene-Containing Dendrimers
Juan-José CID Martin and Jean-François Nierengarten
3.1 Introduction
3.2 Dendrimers with a fullerene core
3.3 Fullerene-rich dendrimers
3.4 Conclusions
Acknowledgements
References
4 Novel Electron Donor Acceptor Nanocomposites
Hiroshi Imahori, Dirk M. Guldi and Shunichi Fukuzumi
4.1 Introduction
4.2 Electron donor-fullerene composites
4.3 Carbon Nanotubes
4.4 Other nanocarbon composites
References
5 Higher Fullerenes: Chirality and Covalent Adducts
Agnieszka Kraszewska, François Diederich, and Carlo Thilgen
5.1 Introduction
5.2 The Chemistry of C70
5.3 The Higher Fullerenes Beyond C70
5.4 Concluding Remarks
Acknowledgements
References
6 Application of Fullerenes to Nanodevices
Yutaka Matsuo and Eiichi Nakamura
6.1 Introduction
6.2 Synthesis of Transition Metal Fullerene Complexes
6.3 Organometallic Chemistry of Metal Fullerene Complexes
6.4 Synthesis of Multimetal Fullerene Complexes
6.5 Supramolecular Structures of Penta(organo)[60]fullerene Derivatives
6.6 Reduction of Penta(organo)[60]fullerenes to Generate Polyanions
6.7 Photoinduced Charge Separation
6.8 Photocurrent-Generating Organic and Organometallic Fullerene Derivatives
6.9 Conclusion
References
7 Supramolecular Chemistry of Fullerenes - Host Molecules for Fullerenes on the Basis of p-p Interaction
Takeshi Kawase
7.1 Introduction
7.2 Fullerenes as an Electron Acceptor
7.3 Host Molecules Composed of Aromatic p-systems
7.4 Complexes with Host Molecules based on Porphyrin p Systems
7.5 Complexes with Host Molecules bearing a Cavity Consisting of Curved p System
7.6 The nature of the Supramolecular property of fullerenes
References
8 Molecular Surgery toward Organic Synthesis of Endohedral Fullerenes
Michihisa Murata, Yasujiro Murata, and Koichi Komatsu
8.1 Introduction
8.2 Molecular-Surgery Synthesis of Endohedral C60 Encapsulating Molecular Hydrogen
8.3 Chemical Functionalization of H2@C60
8.4 Utilization of the Encapsulated H2 as an NMR Probe
8.5 Physical Properties of an Encapsulated H2 in C60
8.6 Molecular-Surgery Synthesis of Endohedral C70 Encapsulating Molecular Hydrogen
8.7 Outlook
References
9 New Endohedral Metallofullerenes: Trimetallic Nitride Endohedral Fullerenes
Marilyn M. Olmstead, Alan L. Balch, Julio R. Pinzon, Luis Echegoyen, Harry W. Gibson and Harry C. Dorn
9.1 Discovery, Preparation and Purification
9.2 Structural Studies
9.3 13C NMR studies of Trimetallic Nitride Endohedral Metallofullerenes (TNT-EMFs)
9.4 Reactivity of Trimetallic Nitride Endohedral Metallofullerenes (TNT-EMFs)
9.5 Summary and conclusions
References
10 Recent Progress in Chemistry of Endohedral Metallofullerenes
Takahiro Tsuchiya, Takeshi Akasaka and Shigeru Nagase
10.1 Introduction
10.2 Chemical derivatization of mono-metallofullerenes
10.3 Chemical derivatization of di-metallofullerenes
10.4 Chemical derivatization of trimetallic nitride template fullerene
10.5 Chemical derivatization of metallic carbaide fullerene
10.6 Missing metallofullerenes
10.7 Supramolecular chemistry
10.8 Conclusion
References
11 Gadonanostructures as Magnetic Resonance Imaging Contrast Agents
Jeyarama S. Ananta and Lon J. Wilson
11.1 Magnetic Resonance Imaging (MRI) and the Role of Contrast Agents (CAs)
11.2 The Advantages of Gadonanostructures as MRI Contrast Agent Synthons
11.3 Gadofullerenes as MRI Contrast agents
11.4 Understanding the Relaxation Mechanism of Gadofullerenes
11.5 Gadonanotubes as MRI Contrast Agents
Acknowledgements
References
12 Chemistry of soluble carbon nanotubes-fundamental and applications
Tsuyohiko Fujigaya and Naotoshi Nakashima
12.1 Introduction
12.2 Characterizations of dispersion state
12.3 Solubilization by small molecules
12.4 Solubilization by polymers
12.5 Nanotube/polymer hybrids/composites
12.6 Summary
References
13 Functionalization of Carbon Nanotubes for Nanoelectronic and Photovoltaic Applications
Stéphane Campidelli and Maurizio Prato
13.1 Introduction
13.2 Functionalization of carbon nanotubes
13.3 Properties and Applications
13.4 Conclusion
References
14 Dispersion and Separation of Single-walled Carbon Nanotubes
Yutaka Maeda, Takeshi Akasaka, Jing Lu and Shigeru Nagase
14.1 Introduction
2. 14.2 Dispersion of SWNTs
3. 14.3 Purification and separation of SWNTs using amine
14.4 Conclusion
15 Molecular Encapsulations into Interior Spaces of Carbon Nanotubes and Nanohorns
T. Okazaki, S. Iijima and M. Yudasaka
15.1 Introduction
15.2 SWCNT nanopeapods
15.3 Material incorporation and release in/from SWNH
15.4 Summary
References
16 Carbon Nanotube for Imaging of Single Molecules in Motion
Eiichi Nakamura
16.1 Introduction
16.2 Electron Microscopic Observation of Small Molecules
16.3 TEM Imaging of Alkyl Carborane Molecules
16.4 Alkyl Chain Passing Through a Hole
16.5 3D Structural Information on Pyrene Amide Molecule
16.6 Complex Molecule 4 Fixed outside of Nanotube
16.7 Conclusion
Acknowledgements
References
17 Chemistry of Single-Nano Diamond Particles
Eiji Ōsawa
17.1 Introduction
17.2 Geometrical Structure
17.3 Electronic Structure
17.4 Properties
17.5 Applications
17.6 Recollection and perspectives
Acknowledgements
References
18 Properties of p-electrons in Graphene Nanoribbons and Nanographenes
De-en Jiang, Xingfa Gao, Shigeru Nagase and Zhongfang Chen
18.1 Introduction
18.2 Edge effects in graphene nanoribbons and nanographenes
18.3 Electronic and magnetic properties of graphene nanoribbons and nanographenes
18.4 Outlook
Acknowledgements
References
19 Carbon Nano Onions
Luis Echegoyen, Angy Ortiz, Manuel N. Chaur and Amit J. Palkar
19.1 Introduction
19.2 Physical Properties of Carbon Nano Onions Obtained from Annealing
19.3 Raman Spectroscopy of Carbon Nano Onions Preparing by Annealing Nanodiamond
19.4 Electron Paramagnetic Resonance Spectroscopy
19.5 Carbon Nano Onions Prepared from Arcing Graphite Underwater
19.6 Reactivity of Carbon Nano Onions (CNOs)
19.7 Potential Applications of CNOs
Acknowledgements
References
Index
LinK
http://ifile.it/863p74o/cnsd8290janmeos.rar
or
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