المصدر: chemistry of Nanocarbons في منتدى : النانوتكنولوجي و المواد النانوية بسم الله الرحمن الرحيم Chemistry of Nanocarbons By Takeshi Akasaka, Fred Wudl, Shigeru Nagase Publisher: Wiley Number Of Pages: 526 Publication Date: 2010-08-17 ISBN-10 / ASIN: 0470721952 ISBN-13 / EAN: 9780470721957 Product Description During the last decade, fullerenes and carbon nanotubes have attracted special interest as new nanocarbons with novel properties. Because of their hollow caged structure, they can be used as containers for atoms and molecules, and nanotubes can be used as miniature test-tubes. Chemistry of Nanocarbons presents the most up-to-date research on chemical aspects of nanometer-sized forms of carbon, with emphasis on fullerenes, nanotubes and nanohorns. All modern chemical aspects are mentioned, including noncovalent interactions, supramolecular assembly, dendrimers, nanocomposites, chirality, nanodevices, host-guest interactions, endohedral fullerenes, magnetic resonance imaging, nanodiamond particles and graphene. The book covers experimental and theoretical aspects of nanocarbons, as well as their uses and potential applications, ranging from molecular electronics to biology and medicine. TABLE OF CONTENTS Preface List of Contributors 1 Noncovalent Functionalization of Carbon Nanotubes Claudia Backes and Andreas Hirsch 1.1 Introduction 1.2 Overview of Functionalization Methods 1.3 The Noncovalent Approach 1.4 Conclusion 2 Supramolecular Assembly of Fullerenes and Carbon Nanotubes Hybrids Mª Ángeles Herranz, Beatriz M. Illescas, Emilio M. Pérez and Nazario Martín 2.1 Introduction 2.2 Hydrogen Bonded C60•Donor ensembles 2.3 Concave exTTF derivatives as recognizing motifs for fullerene 2.4 Non-Covalent Functionalization of Carbon Nanotubes 2.5 Summary and Outlook Acknowledgements References 3 Properties of Fullerene-Containing Dendrimers Juan-José CID Martin and Jean-François Nierengarten 3.1 Introduction 3.2 Dendrimers with a fullerene core 3.3 Fullerene-rich dendrimers 3.4 Conclusions Acknowledgements References 4 Novel Electron Donor Acceptor Nanocomposites Hiroshi Imahori, Dirk M. Guldi and Shunichi Fukuzumi 4.1 Introduction 4.2 Electron donor-fullerene composites 4.3 Carbon Nanotubes 4.4 Other nanocarbon composites References 5 Higher Fullerenes: Chirality and Covalent Adducts Agnieszka Kraszewska, François Diederich, and Carlo Thilgen 5.1 Introduction 5.2 The Chemistry of C70 5.3 The Higher Fullerenes Beyond C70 5.4 Concluding Remarks Acknowledgements References 6 Application of Fullerenes to Nanodevices Yutaka Matsuo and Eiichi Nakamura 6.1 Introduction 6.2 Synthesis of Transition Metal Fullerene Complexes 6.3 Organometallic Chemistry of Metal Fullerene Complexes 6.4 Synthesis of Multimetal Fullerene Complexes 6.5 Supramolecular Structures of Penta(organo)[60]fullerene Derivatives 6.6 Reduction of Penta(organo)[60]fullerenes to Generate Polyanions 6.7 Photoinduced Charge Separation 6.8 Photocurrent-Generating Organic and Organometallic Fullerene Derivatives 6.9 Conclusion References 7 Supramolecular Chemistry of Fullerenes - Host Molecules for Fullerenes on the Basis of p-p Interaction Takeshi Kawase 7.1 Introduction 7.2 Fullerenes as an Electron Acceptor 7.3 Host Molecules Composed of Aromatic p-systems 7.4 Complexes with Host Molecules based on Porphyrin p Systems 7.5 Complexes with Host Molecules bearing a Cavity Consisting of Curved p System 7.6 The nature of the Supramolecular property of fullerenes References 8 Molecular Surgery toward Organic Synthesis of Endohedral Fullerenes Michihisa Murata, Yasujiro Murata, and Koichi Komatsu 8.1 Introduction 8.2 Molecular-Surgery Synthesis of Endohedral C60 Encapsulating Molecular Hydrogen 8.3 Chemical Functionalization of H2@C60 8.4 Utilization of the Encapsulated H2 as an NMR Probe 8.5 Physical Properties of an Encapsulated H2 in C60 8.6 Molecular-Surgery Synthesis of Endohedral C70 Encapsulating Molecular Hydrogen 8.7 Outlook References 9 New Endohedral Metallofullerenes: Trimetallic Nitride Endohedral Fullerenes Marilyn M. Olmstead, Alan L. Balch, Julio R. Pinzon, Luis Echegoyen, Harry W. Gibson and Harry C. Dorn 9.1 Discovery, Preparation and Purification 9.2 Structural Studies 9.3 13C NMR studies of Trimetallic Nitride Endohedral Metallofullerenes (TNT-EMFs) 9.4 Reactivity of Trimetallic Nitride Endohedral Metallofullerenes (TNT-EMFs) 9.5 Summary and conclusions References 10 Recent Progress in Chemistry of Endohedral Metallofullerenes Takahiro Tsuchiya, Takeshi Akasaka and Shigeru Nagase 10.1 Introduction 10.2 Chemical derivatization of mono-metallofullerenes 10.3 Chemical derivatization of di-metallofullerenes 10.4 Chemical derivatization of trimetallic nitride template fullerene 10.5 Chemical derivatization of metallic carbaide fullerene 10.6 Missing metallofullerenes 10.7 Supramolecular chemistry 10.8 Conclusion References 11 Gadonanostructures as Magnetic Resonance Imaging Contrast Agents Jeyarama S. Ananta and Lon J. Wilson 11.1 Magnetic Resonance Imaging (MRI) and the Role of Contrast Agents (CAs) 11.2 The Advantages of Gadonanostructures as MRI Contrast Agent Synthons 11.3 Gadofullerenes as MRI Contrast agents 11.4 Understanding the Relaxation Mechanism of Gadofullerenes 11.5 Gadonanotubes as MRI Contrast Agents Acknowledgements References 12 Chemistry of soluble carbon nanotubes-fundamental and applications Tsuyohiko Fujigaya and Naotoshi Nakashima 12.1 Introduction 12.2 Characterizations of dispersion state 12.3 Solubilization by small molecules 12.4 Solubilization by polymers 12.5 Nanotube/polymer hybrids/composites 12.6 Summary References 13 Functionalization of Carbon Nanotubes for Nanoelectronic and Photovoltaic Applications Stéphane Campidelli and Maurizio Prato 13.1 Introduction 13.2 Functionalization of carbon nanotubes 13.3 Properties and Applications 13.4 Conclusion References 14 Dispersion and Separation of Single-walled Carbon Nanotubes Yutaka Maeda, Takeshi Akasaka, Jing Lu and Shigeru Nagase 14.1 Introduction 2. 14.2 Dispersion of SWNTs 3. 14.3 Purification and separation of SWNTs using amine 14.4 Conclusion 15 Molecular Encapsulations into Interior Spaces of Carbon Nanotubes and Nanohorns T. Okazaki, S. Iijima and M. Yudasaka 15.1 Introduction 15.2 SWCNT nanopeapods 15.3 Material incorporation and release in/from SWNH 15.4 Summary References 16 Carbon Nanotube for Imaging of Single Molecules in Motion Eiichi Nakamura 16.1 Introduction 16.2 Electron Microscopic Observation of Small Molecules 16.3 TEM Imaging of Alkyl Carborane Molecules 16.4 Alkyl Chain Passing Through a Hole 16.5 3D Structural Information on Pyrene Amide Molecule 16.6 Complex Molecule 4 Fixed outside of Nanotube 16.7 Conclusion Acknowledgements References 17 Chemistry of Single-Nano Diamond Particles Eiji Ōsawa 17.1 Introduction 17.2 Geometrical Structure 17.3 Electronic Structure 17.4 Properties 17.5 Applications 17.6 Recollection and perspectives Acknowledgements References 18 Properties of p-electrons in Graphene Nanoribbons and Nanographenes De-en Jiang, Xingfa Gao, Shigeru Nagase and Zhongfang Chen 18.1 Introduction 18.2 Edge effects in graphene nanoribbons and nanographenes 18.3 Electronic and magnetic properties of graphene nanoribbons and nanographenes 18.4 Outlook Acknowledgements References 19 Carbon Nano Onions Luis Echegoyen, Angy Ortiz, Manuel N. Chaur and Amit J. Palkar 19.1 Introduction 19.2 Physical Properties of Carbon Nano Onions Obtained from Annealing 19.3 Raman Spectroscopy of Carbon Nano Onions Preparing by Annealing Nanodiamond 19.4 Electron Paramagnetic Resonance Spectroscopy 19.5 Carbon Nano Onions Prepared from Arcing Graphite Underwater 19.6 Reactivity of Carbon Nano Onions (CNOs) 19.7 Potential Applications of CNOs Acknowledgements References Index LinK or or
لم أستطع النوم وأول شيء عملته هو تشغيل الحاسبة ومباشرة الى هذا القســم! فوجدت هذا الكتاب الجميل بِسْمِ اللّهِ الرَّحْمَنِ الرَّحِيمِ وَلاَ يُحِيطُونَ بِشَيْءٍ مِّنْ عِلْمِهِ إِلاَّ بِمَا شَاء صدق اللّهِ العلي العظيم
