Metal Complexes in Organic Synthesis
Iridium Complexes in Organic Synthesis
By Luis A. Oro, Carmen Claver
Publisher: Wiley-VCH
Number of Pages: 424
Publication Date: 2009-02-24
Book Description
Ranging from hydrogenation to hydroamination, cycloadditions and nanoparticles, this is the first book to comprehensively cover the topic of iridium in organic synthesis by detailing important advances in iridium catalyzed reactions. Iridium is extremely useful in synthesis due to its ability to catalyze an array of synthetic transformations, often with unique selectivity, therefore making this handbook an essential resource for anyone working in the industry
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Ruthenium in Organic Synthesis
By Shun-Ichi Murahashi
Publisher: Wiley-VCH
Number of Pages: 398
Publication Date: 2004-11-10
Book Description:
In this comprehensive book, one of the leading experts, Shun-Ichi Murahashi, presents all the important facets of modern synthetic chemistry using Ruthenium, ranging from hydrogenation to metathesis. In 14 contributions, written by an international authorship, readers will find all the information they need about this fascinating and extraordinary chemistry. The result is a high quality information source and a indispensable reading for everyone working in organometallic chemistry.
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Metal Carbenes in Organic Synthesis
By Florencio Zaragoza Dörwald, Florencio Zaragoza Dorwald
Publisher: Wiley-VCH
Number of Pages: 290
Publication Date: 1999-01-25
Book Description:
There are hardly more versatile compounds in organic synthesis than carbene complexes. The rapid development of new synthetic methods involving carbene complexes - stereoselective cyclopropanation, carbonyl olefination, olefin metathesis, etc. - reveals the value and high potential of these compounds. Their application ranges from the synthesis of fine chemicals to polymer production.
This comprehensive, well structured handbook presents the fundamental principles and the recent advances in carbene complex chemistry. Arranged according to structure and reactivity, all relevant classes of carbene complexes, their generation, and application in organic synthesis are discussed in detail. Critically selected, up-to-date references and valuable experimental procedures await the reader. Every chemist searching for a concise introduction and reference work for carbene complex chemistry will welcome this practical guide.
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Metal Carbenes in Organic Synthesis
By Karl Heinz Dötz
Publisher: Springer
Number of Pages: 377
Publication Date: 2004-12-14
Product Description:
Metal carbene complexes have made their way from organometallic curiosities to valuable reagents and catalysts. They offer novel synthetic opportunities in carbon carbon bond formation based on either carbene-centered reactions or on metal-templated processes which makes them indispensable in modern synthetic methodology. The most prominent metal carbenes are now either commercially available or easy to synthesize and handle by modern laboratory techniques. This volume organized in eight chapters written by the leading scientists in the field illustrates the theoretical background, non-classical nucleophilic and cycloaddition patterns, chromium-templated benzannulation and photo-induced reactions, rhodium-catalyzed carbene transfer as well as the principles and applications of olefin metathesis which coined the progress in synthetic methodology over the past decade. Designed for researchers in academia and industry as well as graduate students it presents the state-of-the-art potential of carbene complexes in modern organic synthesis.
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Transition Metal Arene π-Complexes in Organic Synthesis and Catalysis
By E. Peter Kündig
Publisher: Springer
Number of Pages: 232
Publication Date: 2004-08-05
Book Description:
Metal-arene π-complexes show a rich and varied chemistry. The metal adds a third dimension to the planar aromatic compounds and coordination of a metal to an arene thus not only altering the reactivity of ring-carbons and substituents but also makes possible reactions that lead to chiral non-racemic products. This book, organized in nine chapters and written by leading scientists in the field provides the reader with an up-to-date treatise on the subject organized according to reaction type and use. It covers the wide spectrum of arene activation: from the electrophilic activation of η6-bound arene by pi-Lewis acid metal complex fragments, to reactions of nucleophilic η2-coordinated arene complexes. The preparation of complexes is detailed, as are the scope, limitations and challenges of reactions in contemporary pi-arene metal chemistry with special attention given to asymmetric transformations. The emphasis of the book is on transformations of interest to organic synthesis and on the use of the complexes as catalysts or as chiral ligands.
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Metallocenes in Regio- and Stereoselective Synthesis
By Tamotsu Takahashi
Publisher: Springer
Number of Pages: 244
Publication Date: 2005-01-12
Book Description:
Metallocene is a well known sandwich complex with two cyclopentadienyl ligands such as ferrocene. Recently, such metallocene compounds have been found to be very characteristic and they have become very important, not only in the area of organic synthesis, but also in polymerization in industry. Metal complexes with one cyclopentadienyl ligand have also become popular as half sandwich complexes. The number of researchers in the field of metallocenes has increased rapidly. However, the origin of the characteristic reactivity of metallocenes is not fully understood. In this volume, the chemistry of metal complexes with at least one cyclopentadienyl ligand is comprehensively covered by leading experts. Reactions discussed here are (i) natural product synthesis, (ii) catalytic asymmetric synthesis, (iii) cyclization reactions, (iv)catalytic reactions, (iv) polymerization reactions and (v) carbon-carbon bond cleavage reactions. The reader will have access to useful information about the current state of metallocene chemistry.
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Organolithiums in Enantioselective Synthesis
By David M. Hodgson
Publisher: Springer
Number of Pages: 320
Publication Date: 2003-06-04
Book Description:
Organolithium chemistry occupies a central position in the selective construction of C-C bonds in both simple and complex molecules. Paralleling the surge of interest in methods for asymmetric synthesis, the use of organolithiums in enantioselective synthesis has witnessed spectacular advances in a little over a decade. This volume is the first dedicated to a comprehensive coverage of this important area. It is designed to provide graduate students and researchers with a rich source of essential information on synthesising molecules in an enantioselective manner using organolithiums, and be an inspiration for future developments. Following an overview chapter summarising the key milestones, successive chapters, each written by leading experts in their field, critically survey all the major areas of progress.
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Titanium and Zirconium in Organic Synthesis
By Victor Snieckus, Ilan Marek
Publisher: Wiley-VCH
Number of Pages: 537
Publication Date: 2002-09-09
Book Description:
During the last years, the role of titanium and zirconium in organic synthesis has dramatically increased and nowadays, no synthetic chemist can afford to be without a sound knowledge of this fascinating organometal chemistry.
This unique book, edited by Ilan Marek, thus summarizes the numerous applications and
developments of these two group 4 early transition metal complexes.
A plethora of internationally renowned experts and leading scientists in this field cover all the significant aspects of this increasingly important
part of organic chemistry and bring the reader up to date.
A particularly attractive and useful feature is the inclusion of typical experimental procedures, chosen for broad utility and application.
This comprehensive demonstrates the diversity and the applications of these important compounds and is a must-have for all chemists working in organometallic or synthetic organic chemistry.
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Metal Mediated Template Synthesis of Ligands
By Otilia Costisor, Wolfgang Linert
Publisher: World Scientific Publishing Company
Number of Pages: 308
Publication Date: 2004-06
Book Description:
This book surveys the relatively new area of the synthesis of organic ligands when metal ions act as a template. In the last fifty years this field has undergone an explosive development, marked by a great amount of literature. The material in the book has been arranged according to the type of chemical reaction involved. In this frame, the basic principles of metal template reactions and the shape of the molecules are considered. Designed to satisfy the demands of students, young researchers doing their PhDs, and those working in the field of coordination chemistry, the book details the role of the metal ions and the specific properties of the formed complexes.
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