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:gift::gift:
Organic Reactions- Volume 71
By
Larry E. Overman
Publisher
Wiley-Interscience
Number Of Pages: 772
Publication Date: 2008-06-03
ISBN-10 / ASIN: 0470098996
ISBN-13 / EAN: 9780470098998
BooK Description
For all volumes: the volumes of Organic Reactions are collections of chapters each devoted to a single reaction or a definitive phase of a reaction, of wide applicability. The authors have had experience with the processes surveyed. The subjects are presented from the preparative viewpoint and particular attention is given to limitations, interfering influences, effects of structure and the selection of experimental techniques. Each chapter includes several detailed procedures illustrating the significant modifications of the method. Each chapter contains tablets that include all the examples of the reaction under consideration that the author has been able to find. This volume in the prestigious series includes complete coverage of the catalytic asymmetric Strecker reaction and the preparation of phenols and quinones via Fischer carbene complexes.
Volume 71 contains one chapter: IONIC AND ORGANOMETALLIC-CATALYZED ORGANOSILANE REDUCTIONS
The purpose of this chapter is to present a critical review of synthetically
useful variations of ionic methods for hydrogenation of organic compounds. In
practice, ionic hydrogenation involves the formal introduction of hydride from
a donor source to an electron-deficient carbon center. The electrophilic centers
can be formed by the departure of a leaving group (nucleofuge) from a saturated
center or by the addition of an electrophile to a multiple bond. In the former
mechanism, substitution of hydrogen for the leaving group is the net chemical
consequence. In the latter, addition across the multiple bond is the result.
In this chapter, we cover the use of organosilicon hydrides as the source of
ionic hydride with the goal of completing and updating earlier review works
on the subject.
LinK
http://rapidshare.com/files/247004948/orgarev71.rar
pass: tForgarev71.rar
or
http://rapidshare.com/files/247195926/OrgR71.rar
pass: chem4all.vn
:gift::gift:
Organic Reactions- Volume 71
By
Larry E. Overman
Publisher
Wiley-Interscience
Number Of Pages: 772
Publication Date: 2008-06-03
ISBN-10 / ASIN: 0470098996
ISBN-13 / EAN: 9780470098998
BooK Description
For all volumes: the volumes of Organic Reactions are collections of chapters each devoted to a single reaction or a definitive phase of a reaction, of wide applicability. The authors have had experience with the processes surveyed. The subjects are presented from the preparative viewpoint and particular attention is given to limitations, interfering influences, effects of structure and the selection of experimental techniques. Each chapter includes several detailed procedures illustrating the significant modifications of the method. Each chapter contains tablets that include all the examples of the reaction under consideration that the author has been able to find. This volume in the prestigious series includes complete coverage of the catalytic asymmetric Strecker reaction and the preparation of phenols and quinones via Fischer carbene complexes.
Volume 71 contains one chapter: IONIC AND ORGANOMETALLIC-CATALYZED ORGANOSILANE REDUCTIONS
The purpose of this chapter is to present a critical review of synthetically
useful variations of ionic methods for hydrogenation of organic compounds. In
practice, ionic hydrogenation involves the formal introduction of hydride from
a donor source to an electron-deficient carbon center. The electrophilic centers
can be formed by the departure of a leaving group (nucleofuge) from a saturated
center or by the addition of an electrophile to a multiple bond. In the former
mechanism, substitution of hydrogen for the leaving group is the net chemical
consequence. In the latter, addition across the multiple bond is the result.
In this chapter, we cover the use of organosilicon hydrides as the source of
ionic hydride with the goal of completing and updating earlier review works
on the subject.
LinK
http://rapidshare.com/files/247004948/orgarev71.rar
pass: tForgarev71.rar
or
http://rapidshare.com/files/247195926/OrgR71.rar
pass: chem4all.vn