كيمياء غير عضوية Topics in Organometallic Chemistry Collection

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Topics in Organometallic Chemistry Collection​

Volume 001.Alkene Metathesis in Organic Synthesis
http://rapidshare.com/files/30299328/001.Alkene_Metathesis_in_Organic_Synthesis.rar

Volume 002.Lanthanides Chemistry and Use in Organic Synthesis​

Publisher: Springer
Number Of Pages: 300
Publication Date: 1999-05-15 ​

Description:
The use of lanthanides in organic chemistry and in organic synthesis has attracted broad interest recently because of the unique reactivities and selectivities exhibited by compounds of these rare earth elements. In particular, several major advances have been made in the last five years. This volume of Topics in Organometallic Chemistry is designed to provide the specialist and non-specialist alike with a much needed overview of recent developments. Contributions by leaders in the field focus on stereoselective organic synthesis using lanthanides, the principles of lanthanide chemistry, lanthanide-based chiral catalysts, low-valent lanthanide compounds, polymer synthesis using lanthanide catalysts, and polymer-supported lanthanide catalysts used in organic synthesis.


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Volume 003.Activation of Unreactive Bonds and Organic Synthesis​

Publisher: Springer
Number Of Pages: 272
Publication Date: 1999-07-15​

Description:
In the last few years a large repetoire of methods for the activation of unreactive organic functionalities and for their use in organic synthesis has been developed. In this volume, areas ranging from the activation of C-H bonds to the chemical transformation of dinitrogen are authoritatively discussed by leading experts in the field. To activate means to be able to cleave otherwise inert chemical bonds. The cleavage and formation of chemical bonds is fundamental to organic synthesis; these new activation methodologies make hitherto infeasible reactions extremely easy and create[FONT=arial,helvetica,clean,sans-serif][FONT=arial,helvetica,clean,sans-serif]new [/FONT][/FONT][FONT=arial,helvetica,clean,sans-serif][FONT=arial,helvetica,clean,sans-serif]opportunities [/FONT][/FONT]for innovative organic transformations, for both industry and academia. This is the first book that provides a thorough and timely coverage of both inorganic and organic synthetic aspects of bond activation, thus giving a broad overview of the field and allowing both inorganic and organic chemists ready access to the methodologies involved.

http://rapidshare.com/files/30299701/003.Activation_of_Unreactive_Bonds_and_Organic_Synthesis.rar

Volume 004.Organometallic Bonding and Reactivity -.- Fundamental Studies
http://rapidshare.com/files/30299891/004.Organometallic_Bonding_and_Reactivity_-.-_Fundamental_Studies.rar

Volume 005.Organolithiums in Enantioselective Synthesis

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006 Organometallics in Process Chemistr

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Volume007.Transition Metal Arene pi-Complexes in Organic Synthesis and Catalysts

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Volume 008 Metallocenes in Regio- and Stereoselective Synthesis

http://rapidshare.com/files/30300754/008.Metallocenes_in_Regio-_and_Stereoselective_Synthesis.rar

Volume 009 Precursor Chemistry of Advanced Materials​

Publisher: Springer
Number Of Pages: 213
Publication Date: 2005-11-14 ​

Description:
Material synthesis by the transformation of organometallic compounds (precursors) by vapor deposition techniques such as [FONT=arial,helvetica,clean,sans-serif][FONT=arial,helvetica,clean,sans-serif]chemical [/FONT][/FONT][FONT=arial,helvetica,clean,sans-serif][FONT=arial,helvetica,clean,sans-serif]deposition[/FONT][/FONT][/color][/color][/color] (CVD) and atomic layer deposition (ALD) has been in the forefront of modern day [FONT=arial,helvetica,clean,sans-serif][FONT=arial,helvetica,clean,sans-serif]research [/FONT][/FONT][FONT=arial,helvetica,clean,sans-serif][FONT=arial,helvetica,clean,sans-serif]and [FONT=arial,helvetica,clean,sans-serif]development [/FONT][/FONT][/FONT]of new materials. There exists a need for new routes for designing and synthesizing new precursors as well as the application of established molecular precursors to derive tuneable materials for technological demands. With regard to the precursor chemistry, a most detailed understanding of the mechanistic complexity of materials formation from molecular precursors is very important for further development of new processes and advanced materials. To emphasize and stimulate research in these areas, this volume comprises a selection of case studies covering various key-aspects of the interplay of precursor chemistry with the process conditions of materials formation, particularly looking at the similarities and differences of CVD, ALD and nanoparticle synthesis, e.g. colloid chemistry, involving tailored molecular precursors.

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Volume 010 New Aspects of Zirconium Containing Organic Compounds

http://rapidshare.com/files/30303396/010.New_Aspects_of_Zirconium_Containing_Organic_Compounds.rar

Volume 011 Alkene Metathesis in Organic Synthesis

http://rapidshare.com/files/30304091/011.Ruthenium_Catalysts_and_Fine_Chemistry.rar

Volume 012 Theorectical Aspects of Transition Metal Catalysis

http://rapidshare.com/files/30304463/012.Theorectical_Aspects_of_Transition_Metal_Catalysis.rar

Volume 013 .Metal Carbenes in Organic Synthesis

http://rapidshare.com/files/30304929/013.Metal_Carbenes_in_Organic_Synthesis.rar

Volume 014 .Palladium in Organic Synthesis

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Volume 015 Chiral Diazaligands for Asymmetric Synthesis​

Publisher: Springer
Number Of Pages: 301
Publication Date: 2005-12-01 ​

Description:
The use of phosphine derivatives has historically induced the tremendous development of catalysis (both non-asymmetric and asymmetric). Although the chemistry of amines is more documented, the use of nitrogen-containing ligands only appeared recently. Nevertheless, during the last ten years, the results describing chiral diamine preparations and their uses in asymmetric catalysis and synthesis are increasing faster than their phosphorus counterparts. The reader will find in this volume the most recent methods for the synthesis of chiral diamines as well as their applications in asymmetric catalysis of CC bond formation. Particular attention will be given to spartein and derivatives of such diamines. Recently, the particular properties and the chemistry of amines allowed to obtain catalysts easy to separate and recycle and new types of ligands such as diaminocarbenes, ureas and thioureas. Finally, the complexing properties of some diamines allowed the formation of complexes with chirality "at the metal " which is of major theoretical interest and presents numerous potential applications

http://rapidshare.com/files/30306197/015.Chiral_Diazaligands_for_Asymmetric_Synthesis.rar

Volume 016 Surface and Interfacial Organometallic Chemistry and
Catalysis​

Publisher: Springer
Number Of Pages: 292
Publication Date: 2005-12-19​

Description:
Heterogeneous catalysis has been essential to the development of efficient chemical processes for more than a century, and this field has been traditionally part of the solid state chemistry and surface science communities. The design of better catalysts has raised the following questions: "what is the structure of the active and "how to control their nature?" The necessary need to develop more sustainable chemical processes and the success of homogeneous catalysis relying on molecular organometallic chemistry has led the community of molecular chemists to investigate the preparation of single-site heterogeneous catalysts. The authors discuss the molecular design], the preparation, the characterisation and the catalytic applications of well-defined oxides and metal particles]. The readers will acquire a molecular understanding of heterogeneous catalysis, which will help them develop a critical view and which will attract them to study this fascinating field.

http://rapidshare.com/files/30306611/016.Surface_and_Interfacial_Organometallic_Chemistry_and_Catalysis.rar

Volume 017 Bioorganometallic Chemistry​

Publisher: Springer
Number Of Pages: 222
Publication Date: 2006-07-11​

Description:
Bioorganometallic Chemistry has become a mature area of science and is comprehensively covered by leading experts in this book. Naturally occuring bioorganometallic complexes, such as vitamin B12 and recently discovered iron and nickel hydrogenases, including a possible role of the latter in the geochemical theory of the origin of life, are considered. The possible formation of carbene complexes of cytochrome P450 enzymes in various metabolisms of xenobiotics is also discussed. The bioorganometallic chemistry is considered to provide not only organometallic receptors such as polynuclear organometallic macrocycles for biologically interesting molecules but also ferrocene-peptide bioconjugates giving a peptidomimetic basis for protein folding. The medicinal properties of organometallic compounds are reviewed, with notable applications in the treatment and diagnosis of cancer and in the treatment of viral, fungal, bacterial and parasitic infections. Therefore the reader will get a balanced view of this rapidly developing and promising area.

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Volume 018 Catalytic Carbonylation Reactions

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Volume 019 Metal Catalyzed Cascade Reactions​

Publisher: Springer
Number Of Pages: 339
Publication Date: 2006-08-18 ​

Description:
Transition metal-catalyzed cascade reactions are an elegant approach to complex molecular scaffolds. Besides their esthetics and increase in structural complexity, they have also become mechanistic challenges for the combination of organometallic elementary steps. As a consequence, cascade reactions have revolutionized synthetic strategies and conceptual thinking. The authors highlight cyclization via carbopalladation and acylpalladation and Heck-pericyclic sequences. They discuss p-allyl palladium-based cascade reactions, Michael -type additions as an entry to transition-metal-promoted cyclizative transformations, and sequential or consecutive palladium-catalyzed processes, and show Pauson-Khand cascades, metal-catalyzed cyclizations of acyclic precursors, as well as cascade and sequential ruthenium-catalyzed transformations. Therefore, the reader finds overview of an exciting and highly dynamic field of a new and innovative methodological concept

http://rapidshare.com/files/30309364/019.Metal_Catalyzed_Cascade_Reactions.rar

Volume 020 Dendrimer Catalysis​

Publisher: Springer
Number Of Pages: 189
Publication Date: 2006-10-05​

Description:
Since the first application of dendrimers in catalysis in the mid 1990s, this field has advanced rapidly. As a consequence, catalytically active dendrimers have emerged as a class of molecular catalysts that has substantially enriched the field of homogeneous (and in part heterogeneous) catalysis. A general survey of transition metal dendrimer catalysts and the way they have developed is followed by in-depth discussions of dendritic transition metal catalysis based on non-covalent catalyst-support interaction and an overview of the rapidly growing field of stereoselective dendrimer catalysis. The development of dendrimer-encapsulated bimetallic nanoparticles has provided the interface with heterogeneous colloid catalysis. As cheaper and readily accessible alternatives to regular dendrimers, hyperbranched polymers are increasingly being used as catalyst platforms. These topics are complemented by a review of metallodendritic exoreptors for the redox recognition of oxo-anions and halides.

http://rapidshare.com/files/30310268/020.Dendrimer_Catalysis.rar

Volume 021 N-Heterocyclic Carbenes in Transition Metal Catalysis​

Publisher: Springer
Number Of Pages: 243
Publication Date: 2006-12-20​

Description:
It was only in the early 1990s that carbenes with the carbene carbon being incorporated in a [FONT=arial,helvetica,clean,sans-serif][FONT=arial,helvetica,clean,sans-serif]nitrogen [/FONT][/FONT]containing heterocycle (N-heterocyclic carbenes or NHCs) were found to be stable enough to be isolated. Since the first report on the application of NHCs as ligands in transition metal catalysis in 1995, NHC have found numerous applications and have been established as a versatile and indispensable class of ligands. For many reactions like metathesis or [FONT=arial,helvetica,clean,sans-serif][FONT=arial,helvetica,clean,sans-serif]cross[/FONT][/FONT] -coupling reactions NHCs have often become the ligands of choice, allowing otherwise difficult transformations. In this book leading experts have surveyed major areas of [FONT=arial,helvetica,clean,sans-serif][FONT=arial,helvetica,clean,sans-serif]application[/FONT][/FONT] of NHC metal complexes in catalysis. The authors have placed a special focus on nickel- and palladium-catalyzed reactions, on applications in metathesis reactions, on oxidation reactions and on the use of chiral NHC-based catalysts. This compilation is rounded out by an introductory chapter and a chapter dealing with synthetic routes to NHC metal complexes. The use of NHC as ligands in catalysis has reached a certain level of maturity and this book allows the reader to get a balanced view of this increasingly important ligand class.

http://rapidshare.com/files/30310616/021.N-Heterocyclic_Carbenes_in_Transition_Metal_Catalysis.rar

 

[abu-omar]

Topics in Organometallic Chemistry Collection​

Volume 22: Organometallic Oxidation Catalysis ​

Publisher: Springer
Number Of Pages: 253
Publication Date: 2007-04-04​

Description:
Eighty per cent of all compounds produced in the chemical and pharmaceutical industries require at least one essential catalytic step during their synthesis. At the same time the use of hydrocarbons as a feed-stock for commodity and fine chemicals typically requires an oxidation step, which is usually mediated by a transition metal compound. Consequently oxidation catalysis is a major research field in chemistry, both in academia and in industry. In many such processes, species with metal-carbon bonds are formed as key intermediates, and these processes represent the primary focus of this volume. An important aspect covered by some of the expert contributors is the use of organic ligands - and thus organometallic complex metal fragments - to achieve efficient oxidation catalysis. It has not been self-evident that organometallic complexes can survive the conditions necessary for polar oxygen-transfer reactions, but research over the last decade concerning oxo and peroxo complexes functionalized by organic ligands has clearly shown that relatively non-polar M-C bonds can be quite stable in the presence of oxidants and protic media, and that they may even be essential for the favourable activity and life-time of a catalyst. Also considered in this context is the oxidation chemistry of basic organometallic species in the gas phase, as this may reveal fundamental characteristics inherent to oxidation catalysts.

http://rapidshare.com/files/49020092/qwast.rar
http://mihd.net/7dzlyi/__3528b02__.html

Vomume: Directed Metallation​

Publisher: Springer
Number Of Pages: 206
Publication Date: 2007-12-12 ​

Description:
Directed metalation is recognized as one of the most useful methodologies for the regio- and stereoselective generation of organometallic species , the generation of which necessarily leads to the selective formation of organic products. Cyclometalation using Li, Mn, and Pd, and directed hydrometalation and carbometalation using Al and Zn, have been utilized for regio- and/or stereoselective synthesis for decades. Recently, a new chelation-assisted methodology has been developed not only for controlling regio- and stereoselectivity of reactions, but also for accelerating reactions. In particular, chelation-methodology has been utilized as a new activation method, in which a carbon-metal bond is generated directly from a C-H bond; a reaction rarely achieved using conventional methods. A wide variety of catalytic functionalization reactions of C-H bonds by the utilization of a chelation, have been developed recently and are comprehensively discussed in this book by leading experts. In addition, new approaches to directed hydrometalation and directed carbometalation as a key step are also discussed. A unique [stereo]- and regioselective hydroformylation has been developed through the utilization of directed hydrometalation. The regioselective Mizoroki-Heck reaction is another example in which directed carbometalation can be used to achieve a high regioselectivity. These examples emphasize how these innovative methodologies are contributing to different fields of chemistry.


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New Aspects of Zirconium Containing Organic Compounds

Topics in Organometallic Chemistry Volum 10​

New Aspects of Zirconium Containing Organic Compounds
Ilan Marek​

Publisher: Springer
Number Of Pages: 156
Publication Date: 2005-11-02 ​

Description:

Metal carbene complexes have made their way from organometallic curiosities to valuable reagents and catalysts. They offer novel synthetic opportunities in carbon-carbon bond formation based on either carbene-centered reactions or on metal-templated processes which makes them indispensable in modern synthetic methodology. The most prominent metal carbenes are now either commercially available or easy to synthesize and handle with modern laboratory techniques. This volume organized in eight chapters written by the leading scientists in the field illustrates the theoretical background, non-classical nucleophilic and cycloaddition patterns, chromiu-templated benzannulation and photo-induced reactions, rhodium-catalyzed carbene transfer as well as the principles and applications of olefin metathesis which has coined the progress in synthetic methodology over the past decade. Designed for researchers in academia and industry as well as graduate students it presents the state-of-the-art potential of carbene complexes in modern organic synthesis.​

http://mihd.net/tbpeni/__4128b02__.html
http://rapidshare.com/files/34936679/NAZCO.pdf

 

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