http://www3.interscience.wiley.com/cgi-bin/bookhome/109869932/
Phosgenations - A Handbook
1. Edition - November 2003
239.- Euro
2003. XII, 656 Pages, Hardcover
- Handbook/Reference Book -
ISBN-10: 3-527-29823-1
ISBN-13: 978-3-527-29823-5 - Wiley-VCH, Weinheim
Short description
In this manual, the authors compare the range of applications for phosgene with that of the alternative compounds. The result is a mine of information for synthetic chemists working in industry and academia, dealing with the question of where the toxic phosgene may be replaced by an unproblematic compound - including the safety phosgenation.
From the contents
Introduction. Classification of Phosgene Organic Reactions
Structural Properties of Phosgene and 'Pseudophosgene' Compounds
Thermodynamic of Phosgene Reactions
Thermal, Chemical (Nucleophilic) and Catalytic Induced Dissociation
Phosgenes vs. Phosgene Substitutes Reactivity
Phosgenes vs. Phosgene Substitutes Reactions
Specific Synthetic Applications of Phosgene vs. Phosgene Substitutes
Sources of Phosgene
Synthesis of Phosgene Substitutes
Toxicity
Safety Aspects and Environmental Impact
Monitoring of Phosgene and Phosgene Substitutes. Analytical Methods
Outlook and Conclusions
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