Sulfuric Acid Manufacture

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Sulfuric Acid Manufacture

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Sulfuric Acid Manufacture
By William G.I. Davenport, Matthew King




Publisher: Elsevier Science
Number Of Pages: 425
Publication Date: 2005-12-17
ISBN-10 / ASIN: 0080444288



Product Description:

More sulfuric acid is produced every year than any other chemical. It has a wide range of uses including phosphate fertilizer production, explosives, glue, wood preservatives, and lead-acid batteries. It is also a particularily corrosive and dangerous acid, with extreme environmental and health hazards if not manufactured, used, and regulated properly.

Sulfuric Acid Manufacture: Analysis, Control and Optimization keeps the important topics of safety and regulation at the forefront as it overviews and analyzes the process of sulfuric acid manufacture.

The first nine chapters focus on the chemical plant processes involved in industrial acidmaking, with considerable data input from the authors' industrial colleagues. The last 15 chapters are dedicated to the mathematical analysis of acidmaking.

Both Authors bring years of hands-on knowledge and experience to the work, making it an exceptional reference for anyone involved in sulfuric acid research and/or manufacture.

Only book to examine the processes of sulfuric acid manufacture from an industrial plant standpoint as well as mathematical.

Draws on the industrial connections of the authors, through their years of hands-on experience in sulfuric acid manufacture.

A considerable amount of industrial plant data is presented to support the text.

Preface, Pages v-vi
Chapter 1 - Overview, Pages 1-10
Chapter 2 - Production and Consumption, Pages 11-18
Chapter 3 - Sulfur Burning, Pages 19-30
Chapter 4 - Metallurgical Off gas Cooling and Cleaning, Pages 31-45
Chapter 5 - Regeneration of Spent Sulfuric Acid, Pages 47-57
Chapter 6 - Dehydrating Air and Gases with Strong Sulfuric Acid, Pages 59-69
Chapter 7 - Catalytic Oxidation of SO2 to SO3, Pages 71-88
Chapter 8 - SO2 Oxidation Catalyst and Catalyst Beds, Pages 89-98
Chapter 9 - Production of H2SO4(l) from SO3(g), Pages 99-118
Chapter 10 - Oxidation of SO2 to SO3 — Equilibrium Curves, Pages 119-128
Chapter 11 - SO2 Oxidation Heatup Paths, Pages 129-146
Chapter 12 - Maximum SO2 Oxidation: Heatup Path-Equilibrium Curve Intercepts, Pages 147-158
Chapter 13 - Cooling 1st Catalyst Bed Exit Gas, Pages 159-164
Chapter 14 - 2nd Catalyst Bed Heatup Path, Pages 165-175
Chapter 15 - Maximum SO2 Oxidation in a 2nd Catalyst Bed, Pages 177-182
Chapter 16 - 3rd Catalyst Bed SO2 Oxidation, Pages 183-188
Chapter 17 - SO3 and CO2 in Feed Gas, Pages 189-198
Chapter 18 - 3 Catalyst Bed Acid Plant, Pages 199-210
Chapter 19 - After-H2SO4-Making SO2 Oxidation, Pages 211-228
Chapter 20 - Optimum Double Contact Acidmaking, Pages 229-234
Chapter 21 - Enthalpies and Enthalpy Transfers, Pages 235-242
Chapter 22 - Control of Gas Temperature by Bypassing, Pages 243-251
Chapter 23 - H2SO4 Making, Pages 253-269
Chapter 24 - Acid Temperature Control and Heat Recovery, Pages 271-286

Appendix A - Sulfuric Acid Properties, Pages 287-292
Appendix B - Derivation of Equilibrium Equation (10.12), Pages 293-303
Appendix C - Free Energy Equations for Equilibrium Curve Calculations, Pages 304-305
Appendix D - Preparation of Fig. 10.2 Equilibrium Curve, Pages 306-308
Appendix E - Proof that Volume% = Mole% (for Ideal Gases), Pages 309-310
Appendix F - Effect of CO2 and Ar on Equilibrium Equations (None), Pages 311-315
Appendix G - Enthalpy Equations for Heatup Path Calculations, Pages 316-319
Appendix H - Matrix Solving Using Tables 11.2 and 14.2 as Examples, Page 320-321
Appendix I - Enthalpy Equation in Heatup Path Matrix Cells, Pages 322-324
Appendix J - Heatup Path-Equilibrium Curve Intercept Calculations, Pages 326-332
Appendix K - 2nd Catalyst Bed Heatup Path Calculations, Pages 333-335
Appendix L - Equilibrium Equation for Multi-Catalyst Bed SO2 Oxidation, Pages 336-338
Appendix M - 2nd Catalyst Bed Intercept Calculations, Pages 339-343
Appendix N - 3rd Catalyst Bed Heatup Path Worksheet, Pages 344-345
Appendix O - 3rd Catalyst Bed Intercept Worksheet, Pages 346-347
Appendix P - Effect of SO3 in Fig. 10.1 Feed Gas on Equilibrium Equations, Pages 348-354
Appendix Q - SO3-in-Feed-Gas Intercept Worksheet, Pages 356-357
Appendix R - CO2- and SO3-in-Feed-Gas Intercept Worksheet, Pages 358-359
Appendix S - 3-Catalyst-Bed ‘Converter’ Calculations, Pages 360-366
Appendix T - Worksheet for Calculating After-Intermediate-H2SO4-Making Heatup Path Equilibrium Curve Intercepts, Pages 367-368
Appendix U - After-H2SO4-Making SO2 Oxidation with SO3 and CO2 in Input Gas, Pages 370-374
Appendix V - Moist Air in H2SO4 Making Calculations, Pages 375-377
Appendix W - Calculation of H2SO4 Making Tower Mass Flows, Pages 378-381
Answers to Numerical Problems, Pages 383-394
Author Index, Pages 395-396
Index, Pages 397-413

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