Chemical Kinetics and Reaction Dynamics By Santosh K. Upadhyay
Book Description Chemical Kinetics and Reaction Dynamics brings together the major facts and theories relating to the rates with which chemical reactions occur from both the macroscopic and microscopic point of view. This book helps the reader achieve a thorough understanding of the principles of chemical kinetics and includes: Detailed stereochemical discussions of reaction stepsClassical theory based calculations of state-to-state rate constantsA collection of matters on kinetics of various special reactions such as micellar catalysis, phase transfer catalysis, inhibition processes, oscillatory reactions, solid-state reactions, and polymerization reactions at a single source. The growth of the chemical industry greatly depends on the application of chemical kinetics, catalysts and catalytic processes. This volume is therefore an invaluable resource for all academics, industrial researchers and students interested in kinetics, molecular reaction dynamics, and the mechanisms of chemical reactions
Product details Publisher: Springer Number Of Pages: 256 Publication Date: 2006-12 Sales Rank: 800568 ISBN / ASIN: 1402045468
Book Description The range of courses requiring a good basic understanding of chemical kinetics is extensive, ranging from chemical engineers and pharmacists to biochemists and providing the fundamentals in chemistry. Due to the wide reaching nature of the subject readers often struggle to find a book which provides in-depth, comprehensive information without focusing on one specific subject too heavily.
Here Dr Margaret Wright provides an essential introduction to the subject guiding the reader through the basics but then going on to provide a reference which professionals will continue to dip in to through their careers. Through extensive worked examples, Dr Wright, presents the theories as to why and how reactions occur, before examining the physical and chemical requirements for a reaction and the factors which can influence these.
* Carefully structured, each chapter includes learning objectives, summary sections and problems.
* Includes numerous applications to show relevance of kinetics and also provides plenty of worked examples integrated throughout the text. Product Details
Paperback: 462 pages Publisher: Wiley-Interscience; 1 edition (June 25, 2004) Language: English ISBN-10: 0470090596 ISBN-13: 978-0470090596 Product Dimensions: 9.5 x 6.6 x 1 inches Shipping Weight: 1.7 pounds
Kinetics of Homogeneous Multistep Reactions (Comprehensive Chemical Kinetics) by Friedrich G. Helfferich
Book Description
Hardbound. This book addresses primarily the chemist and engineer in industrial research and process development, where competitive pressures put a premium on scale-up by large factors to cut development time. To be safe, such scale-up should be based on "fundamental" kinetics, that is, mathematics that reflect the elementary steps of which the reactions consist. The book forges fundamental kinetics into a practical tool by presenting new effective methods for elucidation of mechanisms and reduction of mathematical complexity without unacceptable sacrifice in accuracy.
For elucidation of pathways and networks, the book provides a host of new rules relating typical network configurations to observable kinetic behavior. Any configuration producing behavior contrary to observation cannot be correct, so incorrect networks can be rejected by whole classes instead of one by one. For modeling, the book provides general equations and algorithms applicable t Product Details Hardcover: 426 pages Publisher: Elsevier Science; 1 edition (January 1, 2001) Language: English ISBN-10: 0444826068 ISBN-13: 978-0444826060 Product Dimensions: 9.6 x 6.7 x 0.9 inches Shipping Weight: 2.1 pounds
Principles of Chemical Kinetics, Second Edition (Hardcover)
by James E. House
Contents 1. Some Fundamental Ideas of Kinetics
1.1 Rates of Reactions
1.2 Dependence on Concentration
1.3 Cautions on Treating Kinetic Data
1.4 Effect of Temperature
1.5 Some Common Reaction Mechanisms
1.6 Catalysis 2. Kinetics of More Complex Systems
2.1 Second-Order Case, First-Order in Two Components
2.2 Third-Order Reactions
2.3 Parallel First-Order Reactions
2.4 Series First-Order Reactions
2.5 Series Reactions with Two Intermediates
2.6 Reversible Reactions
2.7 Autocatalysis
2.8 Effect of Temperature 3. Techniques and Methods
3.1 Calculating Rate Constants
3.2 The Method of Half-Lives
3.3 Initial Rates
3.4 Using Large Excess of a Reactant (Flooding)
3.5 The Logarithmic Method
3.6 Effects of Pressure
3.7 Flow Techniques
3.8 Relaxation Techniques
3.9 Tracer Methods
3.10 Kinetic Isotope Effects 4. Reactions in the Gas Phase
4.1 Collision Theory
4.2 The Potential Energy Surface
4.3 Transition State Theory
4.4 Unimolecular Decomposition of Gases
4.5 Free Radical or Chain Mechanisms
4.6 Adsorption of Gases on Solids
4.7 Catalysis 5. Reactions in Solutions
5.1 The Nature of Liquids (HSIP)
5.2 Effects of Solvent Polarity on Rates
5.3 Ideal Solutions
5.4 Cohesion Energies of Ideal Solutions
5.5 Effects of Solvent Cohesion Energies on Rates
5.6 Solvation and Its Effects on Rates
5.7 Effects of Ionic Strength
5.8 Linear Free Energy Relationships
5.9 The Compensation Effect
5.10 Some Correlations of Rates with Solubility Parameter 6. Enzyme Catalysis
6.1 Enzyme Action
6.2 Kinetics of Reactions Catalyzed by Enzymes
6.3 Inhibition of Enzyme Action
6.4 The Effect of pH
6.5 Enzyme Activation by Metal Ions
6.6 Regulatory Enzymes 7. Kinetics of Reactions in the Solid State
7.1 Some General Considerations
7.2 Factors Affecting Reactions in Solids
7.3 Rate Laws for Reactions in Solids
7.4 The Prout-Tompkins Equation
7.5 Rate Laws Based on Nucleation
7.6 Applying Rate Laws
7.7 Results of Some Kinetic Studies 8. Nonisothermal Methods in Kinetics
8.1 TGA and DSC Methods
8.2 Kinetic Analysis by the Coats and Redfern Method
8.3 The Reich and Stivala Method
8.4 A Method Based on Three (?N,T) Data Pairs
8.5 A Method Based on Four (?N,T) Data Pairs
8.6 A Differential Method
8.7 A Comprehensive Nonisothermal Kinetic Method
8.8 The General Rate Law and A Comprehensive Method 9. Additional Applications of Kinetics
9.1 Radioactive Decay
9.2 Mechanistic Implications of Orbital Symmetry
9.3 A Further Look at Solvent Polarity and Rates
Book Description James House's revised Principles of Chemical Kinetics provides a clear and logical description of chemical kinetics in a manner unlike any other book of its kind. Clearly written with detailed derivations, the text allows students to move rapidly from theoretical concepts of rates of reaction to concrete applications.
Unlike other texts, House presents a balanced treatment of kinetic reactions in gas, solution, and solid states. The entire text has been revised and includes many new sections and an additional chapter on applications of kinetics. The topics covered include quantitative relationships between molecular structure and chemical activity, organic/inorganic chemistry, biochemical kinetics, surface kinetics and reaction mechanisms. Chapters also include new problems, with answers to selected questions, to test the reader's understanding of each area. A solutions manual with answers to all questions is available for instructors.
A useful text for both students and interested readers alike, Dr. House has once again written a comprehensive text simply explaining an otherwise complicated subject.
* Provides an introduction to all the major areas of kinetics and demonstrates the use of these concepts in real life applications
* Detailed derivations of formula are shown to help students with a limited background in mathematics
* Presents a balanced treatment of kinetics of reactions in gas phase, solutions and solids
* Solutions manual available for instructors Product Details Hardcover: 336 pages Publisher: Academic Press; 2 edition (August 15, 2007) Language: English ISBN-10: 0123567874 ISBN-13: 978-0123567871 Product Dimensions: 8.9 x 6.2 x 1 inches Shipping Weight: 1.4 pounds
Chemical Kinetics: The Study of Reaction Rates in Solution (Paperback) by Kenneth A. Connors
Book Description
Chemical Kinetics The Study of Reaction Rates in Solution Kenneth A. Connors This chemical kinetics book blends physical theory, phenomenology and empiricism to provide a guide to the experimental practice and interpretation of reaction kinetics in solution. It is suitable for courses in chemical kinetics at the graduate and advanced undergraduate levels. This book will appeal to students in physical organic chemistry, physical inorganic chemistry, biophysical chemistry, biochemistry, pharmaceutical chemistry and water chemistry—all fields concerned with the rates of chemical reactions in the solution phase.
The publisher, John Wiley & Sons
This chemical kinetics book blends physical theory, phenomenology and empiricism to provide a guide to the experimental practice and interpretation of reaction kinetics in solution. It is suitable for courses in chemical kinetics at the graduate and advanced undergraduate levels. --This text refers to an out of print or unavailable edition of this title.
Product Details
Paperback: 496 pages Publisher: Wiley-VCH; New Ed edition (August 15, 1990) Language: English ISBN-10: 0471720208 ISBN-13: 978-0471720201 Product Dimensions: 9 x 6.1 x 1.2 inches Shipping Weight: 1.6 pounds
Book Description
Comprehensive manual embracing essentially all the classical and modern areas of chemical kinetics. Provides details of modern applications in chemistry, technology and biochemistry.
Special sections of the book treat subjects not covered sufficiently in other manuals, including: modern methods of experimental determination of rate constants of reactions including laser pico- and femtochemistry, magnetochemistry, and ESR; and descriptions of advanced theories of elementary chemical processes.
- Comprehensive manual covering practically all areas of chemical kinetics, both classical and modern.
- Adequate coverage given to topics not covered sufficiently by other works.
- Covers fundamentals and recent developments in homogeneous catalysis and its modeling from a chemical kinetics perspective.
Book Info
Text presents the basis of chemical kinetics in combination with its modern applications in chemistry, technology, and biochemistry. For scientists working in various areas of chemistry and chemical biotechnology. Product Details
Hardcover: 566 pages Publisher: Elsevier Science; 1 edition (May 23, 2003) Language: English ISBN-10: 0444509380 ISBN-13: 978-0444509383 Product Dimensions: 8.9 x 6 x 1.1 inches Shipping Weight: 2.2 pounds
M. Mortimer, P.G. Taylor, "Chemical Kinetics and Mechanism" Royal Society of Chemistry | 2002-08-12 | ISBN: 0854046704 | 250 pages | PDF | 20,7 MB
Chemical Kinetics and Mechanism considers the role of rate of reaction. It begins by introducing chemical kinetics and the analysis of reaction mechanism, from basic well-established concepts to leading edge research. Organic reaction mechanisms are then discussed, encompassing curly arrows, nucleophilic substitution and E1 and E2 elimination reactions. The book concludes with a Case Study on Zeolites, which examines their structure and internal dimensions in relation to their behaviour as molecular sieves and catalysts. The Molecular World series provides an integrated introduction to all branches of chemistry for both students wishing to specialise and those wishing to gain a broad understanding of chemistry and its relevance to the everyday world and to other areas of science.
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