بسم الله الرحمن الرحيم
Water-Chemistry: An Introduction to_Chemistry*of *Natural
and Engineered_Aquatic Systems
by
Patrick Brezonik, William Arnold
Contents
Preface ix
Acknowledgments xiii
Symbols and Acronyms xv
Symbols xv
Acronyms xviii
Units and Constants xxiii
Units for physical quantities xxiii
Important constants xxiii
Conversion Factors xxv
Energy-related quantities xxv
Pressure xxv
Some useful relationships xxv
Part I Prologue 3
1 Introductory Matters 5
2 Inorganic Chemical Composition of Natural Waters: Elements of Aqueous Geochemistry 41
Part II Theory, Fundamentals, and Important Tools 77
3 The Thermodynamic Basis for Equilibrium Chemistry 79
4 Activity-Concentration Relationships 116
5 Fundamentals of Chemical Kinetics 144
6 Fundamentals of Organic Chemistry for Environmental Systems 189
7 Solving Ionic Equilibria Problems 220
Part III Inorganic Chemical Equilibria and Kinetics 265
8 Acid-Base Systems 267
9 Complexation Reactions and Metal Ion Speciation 311
10 Solubility: Reactions of Solid Phases with Water 364
11 Redox Equilibria and Kinetics 406
Part IV Chemistry of Natural Waters and Engineered Systems 449
12 Dissolved Oxygen 451
13 Chemistry of Chlorine and Other Oxidants/Disinfectants in Water Treatment 482
14 An Introduction to Surface Chemistry and Sorption 518
15 Aqueous Geochemistry II: The Minor Elements: Fe, Mn, Al, Si; Minerals and Weathering 558
16 Nutrient Cycles and the Chemistry of Nitrogen and Phosphorus 601
17 Fundamentals of Photochemistry and Some Applications in Aquatic Systems 637
18 Natural Organic Matter and Aquatic Humic Matter 672
19 Chemistry of Organic Contaminants 713
Appendix Free Energies and Enthalpies of Formation of Common
Chemical Species in Water 758
Subject Index 7
Preface ix
Acknowledgments xiii
Symbols and Acronyms xv
Symbols xv
Acronyms xviii
Units and Constants xxiii
Units for physical quantities xxiii
Important constants xxiii
Conversion Factors xxv
Energy-related quantities xxv
Pressure xxv
Some useful relationships xxv
Part I Prologue 3
1 Introductory Matters 5
2 Inorganic Chemical Composition of Natural Waters: Elements of Aqueous Geochemistry 41
Part II Theory, Fundamentals, and Important Tools 77
3 The Thermodynamic Basis for Equilibrium Chemistry 79
4 Activity-Concentration Relationships 116
5 Fundamentals of Chemical Kinetics 144
6 Fundamentals of Organic Chemistry for Environmental Systems 189
7 Solving Ionic Equilibria Problems 220
Part III Inorganic Chemical Equilibria and Kinetics 265
8 Acid-Base Systems 267
9 Complexation Reactions and Metal Ion Speciation 311
10 Solubility: Reactions of Solid Phases with Water 364
11 Redox Equilibria and Kinetics 406
Part IV Chemistry of Natural Waters and Engineered Systems 449
12 Dissolved Oxygen 451
13 Chemistry of Chlorine and Other Oxidants/Disinfectants in Water Treatment 482
14 An Introduction to Surface Chemistry and Sorption 518
15 Aqueous Geochemistry II: The Minor Elements: Fe, Mn, Al, Si; Minerals and Weathering 558
16 Nutrient Cycles and the Chemistry of Nitrogen and Phosphorus 601
17 Fundamentals of Photochemistry and Some Applications in Aquatic Systems 637
18 Natural Organic Matter and Aquatic Humic Matter 672
19 Chemistry of Organic Contaminants 713
Appendix Free Energies and Enthalpies of Formation of Common
Chemical Species in Water 758
Subject Index 7
