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Organic Chemistry Reference Lectures
Video and Related Text | 2000, 2002 Claude E. Wintner | ISO | 2.56 GB
Misc E Learning
Acknowledgment
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Lecture 1 Introduction
1.01 Foreword ( video )
1.02 Methane ( video, related text )
1.03 Saturated Hydrocarbons ( video, related text )
1.04 Structure Isomers ( video, related text )
Lecture 2 Conformation
2.01 Ethane ( video, related text )
2.02 Propane ( video, related text )
2.03 n Butane ( video, related text )
2.04 n Pentane ( video, related text )
Lecture 3 Constitution
3.01 Review ( video)
3.02 Butane and Isobutane ( video, related text )
3.03 C5H12 Hydrocarbons ( video, related text )
3.04 C6H14 Hydrocarbons ( video, related text )
3.05 C7H16 Hydrocarbons ( video, related text )
Lecture 4 Configuration
4.01 Enantiomerism ( video, related text )
4.02 Introduction to CIP ( video, related text )
4.03 CIP Mechanics ( video, related text )
4.04 Diastereoisomerism: 3,4 Dimethylheptane ( video, related text )
4.05 Achiral Diastereoisomers: 3,4 Dimethylhexane ( video, related text )
4.06 A More Complicated Case: 3,4,5 Trimethylheptane ( video, related text )
Lecture 5 Hydrocarbon Rings
5.01 Introduction to Rings ( video, related text )
5.02 Strain Energy ( video, related text )
5.03 Dimethyl Cyclopropanes ( video, related text )
5.04 Dimethyl Cyclobutanes ( video, related text )
5.05 Cyclohexane Chair Conformation ( video, related text )
5.06 Dimethyl Cyclohexanes ( video, related text )
Lecture 6 Stereotopism
6.01 Constitutionally Distinguishable Groups ( video, related text )
6.02 Homotopic Groups ( video, related text )
6.03 Enantiotopic Groups ( video, related text )
6.04 Diastereotopic Groups ( video, related text )
6.05 Stereotopism in 3,5 Dimethyl heptane ( video, related text )
6.06 Re and Si Faces and Spaces ( video, related text )
6.07 Stereotopism in Ethanol ( video, related text )
Lecture 7 Carbon Bonding
7.01 Hydrogen Molecule ( video, related text, related text: addendum)
7.02 Csp3 Bonding Methane ( video, related text )
7.03 Csp2 Bonding Ethylene ( video, related text )
7.04 Csp2 Bonding Ethylene, continued ( video, related text )
7.05 Csp Bonding Acetylene ( video, related text )
7.06 Allene (1,2 Propadiene) ( video, related text )
7.07 Tau Bonds (Bent Bonds) ( video, related text )
7.08 E/Z Nomenclature ( video, related text )
Lecture 8 Bonding in Carbon Polyene Systems
8.01 1,3 Butadiene ( video, related text )
8.02 1,3,5 Hexatriene ( video, related text )
8.03 The Special Case of Benzene ( video, related text )
8.04 The Generalized Concept of Aromaticity ( video, related text )
8.05 Hexatriene Cyclohexadiene Interconversion ( video, related text )
8.06 Butadiene Cyclobutene Interconversion ( video, related text )
Lecture 9 Basic Ideas of Thermodynamics and Kinetics
9.01 Simple Application of Gibbs Equation ( video, related text )
9.02 Simple Application of Eyrings Equation ( video, related text )
9.03 Thermodynamic vs. Kinetic Control of a Reaction ( video, related text )
Lecture 10 Functionality
10.01 The Concepts Primary, Secondary, Tertiary ( video, related text )
Lecture 11 Acidity and Basicity
11.01 Aqueous Acids and Bases pKA ( video, related text )
11.02 The Lewis Nucleophile Electrophile Definition ( video, related text )
11.03 Avoiding Error When Invoking Aqueous Acids and Bases ( video, related text )
11.04 Potential Delocalization of an Anion Affects Acidity ( video, related text )
11.05 Kinetic vs. Thermodynamic (Equilibrium) Acidity ( video, related text )
11.06 Nucleophilicity vs. Basicity ( video, related text )
Lecture 12 Oxidation and Reduction: Forms of Writing Reactions
12.01 Balancing Redox Reactions ( video, related text )
12.02 Reduction of Alkenes Forms of Writing Reactions ( video, related text )
12.03 Oxidation of Alkenes to Oxiranes (Epoxides) ( video, related text )
12.04 Oxidation of Alkenes to 1,2 Diols (Cis Oxidation) ( video, related text )
12.05 Diastereoselectivity in Redox Reactions ( video, related text )
12.06 Enantioselectivity in Redox Reactions ( video, related text )
Lecture 13 Bimolecular Nucleophilic Substitution and Elimination Reactions
13.01 Bimolecular Nucleophilic Substitution ( video, related text )
13.02 The SN2 Mechanism ( video, related text )
13.03 The Special Case of Primary Halide Synthesis ( video, related text )
13.04 Steric Effects on the SN2 Mechanism ( video, related text )
13.05 The E2 Mechanism Competes with SN2 ( video, related text )
13.06 Stereochemistry of the E2 Reaction ( video, related text )
13.07 Synthesis of Isopropyl Methyl Ether ( video, related text )
Lecture 14 Unimolecular Nucleophilic Substitution and Elimination Reactions
14.01 The SN1 Mechanism ( video, related text )
14.02 Carbocations ( video, related text )
14.03 Synthesis of tert Butyl Methyl Ether ( video, related text )
14.04 The E1 Mechanism ( video, related text )
14.05 Summary of Nucleophilic Substitution Reactions ( video, related text )
Lecture 15 Electrophilic Addition to Alkenes
15.01 Addition of HX to Alkenes ( video, related text )
15.02 Acid Catalyzed Polymerization of Alkenes ( video, related text )
15.03 Epoxidation of cis 2 Butene ( video, related text )
15.04 Epoxidation of trans 2 Butene ( video, related text )
15.05 Bromination of Alkenes ( video, related text )
15.06 Stereochemistry of Bromine Elimination vs. Addition ( video )
15.07 Electrophilic Aromatic Substitution ( video, related text )
Lecture 16 Introduction to the Carbonyl Group
16.01 Introduction to Carbonyl Bonding and Reactivity ( video, related text )
16.02 Introduction to Carbonyl Nomenclature ( video )
16.03 Reaction of the Carbonyl Group with Electrophiles and with Nucleophiles ( video )
16.04 Nucleophilic Addition to the Carbonyl Group vs. Nucleophilic Substitution at Carbonyl ( video, related text )
Lecture 17 Alcohol Synthesis via Nucleophilic Addition to the Carbonyl Group
17.01 Oxidation Reactions of Alcohols to Carbonyl Derivatives ( video )
17.02 Reduction of Aldehydes and Ketones to Alcohols with LiAlH4 and NaBH4 ( video, related text )
17.03 Grignard Reagents Nucleophiles for Carbonyl Addition ( video )
17.04 A General Synthesis of Alcohols ( video, related text )
17.05 Synthesis of 3 Hexanol ( video )
17.06 Synthesis of 3 Methyl 3 Hexanol ( video, related text )
17.07 Diastereoselective Alcohol Syntheses and the Possibility of Enantioselective Alcohol Syntheses ( video, related text )
Lecture 18 Further Nucleophilic Addition Reactions to the Carbonyl Group
18.01 Hydrates ( video, related text )
18.02 Acetals and Ketals ( video, related text )
18.03 Imines, Oximes, Hydrazones ( video, related text )
18.04 Addition of Cyanide Anion to the Carbonyl and Imine Functionalities a Hydroxy Acids and a Amino Acids ( video, related text )
Lecture 19 Nucleophilic Substitution at the Carbonyl Group
19.01 Carboxylic Acids Formation and Activation ( video, related text )
19.02 Esters Formation ( video, related text )
19.03 Esters Hydrolysis and Transesterification ( video, related text )
19.04 Reactions of Esters with Grignard and Hydride Reagents ( video, related text )
19.05 Amides Formation ( video, related text )
19.06 Amides Hydrolysis ( video, related text )
19.07 Nitriles and their Hydrolysis to Amides and Carboxylic Acids Tautomers ( video, related text )
Lecture 20 Consequences of Hydrogen Acidity at Carbonyl a Carbon Aldol and Related Reactions
20.01 Enolate and Enol ( video, related text )
20.02 Tau Bond Interpretation of Enolate Formation ( video, related text )
20.03 Aldol Condensation ( video, related text )
20.04 Aldol Condensation, Continued ( video, related text )
20.05 Claisen (Ester) Condensation Dieckmann Condensation ( video, related text )
20.06 Alkylation and Decarboxylation of b Ketoesters ( video, related text )
20.07 Uses of the Claisen ( video, related text )
20.08 Michael Reaction ( video, related text )
20.09 Robinson Annulation ( video, related text )
Lecture 21 Brief Introduction to Carbohydrates
21.01 Glucaric Acid is Chiral ( video )
21.02 Ruff Degradation Arabaric Acid is Chiral ( video )
21.03 Kiliani Synthesis Glucose and Mannose are C 2 Epimers ( video )
21.04 Mannaric Acid is Chiral. Osazones ( video )
21.05 Emil Fischers Solution to the Glucose Problem ( video )
21.06 Glucose Exists Predominantly in a Glucopyranose Ring ( video )
21.07 Proof of Structure of 2,3,4,6 Tetramethylglucose ( video )
21.08 How to Transform the Glucopyranose Structure into itsProper and Conventional Chair Conformational Rendering ( video )
21.09 Furanose Rings ( video )
21.10 Disaccharides Lactose ( video )
21.11 Polysaccharides Cellulose and Starch ( video )
Lecture 22 Important General Subjects for Review
22.01 The Concept of Retrosynthetic Analysis ( video )
22.02 Writing Mechanisms in Organic Chemistry The Notational Device of Curved Arrow Pushing ( video )
22.03 A Concluding Word ( video )
All video segments 2000 Claude E. Wintner
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